Method of Forming Semiconductor Device

ABSTRACT

A method of fabricating a semiconductor device includes forming a first film having a first film stress type and a first film stress intensity over a substrate and forming a second film having a second film stress type and a second film stress intensity over the first film. The second film stress type is different than the first film stress type. The second film stress intensity is about same as the first film stress intensity. The second film compensates stress induced effect of non-flatness of the substrate by the first film.

PRIORITY DATA

The present application claims priority to U.S. Provisional PatentApplication Ser. No. 62/329,077 filed Apr. 28, 2016, entitled “A METHODOF FORMING SEMICONDUCTOR DEVICE,” the entire disclosure of which ishereby incorporated herein by reference.

BACKGROUND

The semiconductor integrated circuit (IC) industry has experienced rapidgrowth. Technological advances in IC design and material have producedgenerations of ICs where each generation has smaller and more complexcircuits than previous generations. In the course of IC evolution,functional density (i.e., the number of interconnected devices per chiparea) has generally increased while geometry size (i.e., the smallestcomponent (or line) that can be created using a fabrication process) hasdecreased.

This scaling down process generally provides benefits by increasingproduction efficiency and lowering associated costs. Such scaling downhas also increased the complexity of IC processing and manufacturing.For these advances to be realized, similar developments in IC processingand manufacturing are needed. Although existing methods of fabricatingIC devices have been generally adequate for their intended purposes,they have not been entirely satisfactory in all respects. For example,challenges arise when adequate flatness of a substrate is not maintainedduring fabrication.

BRIEF DESCRIPTION OF THE DRAWINGS

Aspects of the present disclosure are best understood from the followingdetailed description when read in association with the accompanyingfigures. It is noted that, in accordance with the standard practice inthe industry, various features in drawings are not drawn to scale. Infact, the dimensions of illustrated features may be arbitrarilyincreased or decreased for clarity of discussion.

FIG. 1 is a flowchart of an example method for fabricating asemiconductor device constructed in accordance with some embodiments.

FIG. 2 is a cross-sectional view of a structure in accordance with someembodiments.

FIG. 3A is a cross-sectional view of an example semiconductor device inaccordance with some embodiments.

FIG. 39 is an energy-dispersive X-ray spectroscopy (EDX) spectrum,constructed according to various embodiments in accordance with someembodiments.

FIGS. 4, 5A, 5B, 6, 7 and 8 are cross-sectional views of an examplesemiconductor device in accordance with some embodiments.

FIG. 9 is a cross-sectional view of another embodiment of asemiconductor substrate according to some embodiments of the presentdisclosure.

DETAILED DESCRIPTION

The following disclosure provides many different embodiments, orexamples, for implementing different features of the invention. Specificexamples of components and arrangements are described below to simplifythe present disclosure. These are, of course, merely examples and arenot intended to be limiting. For example, the formation of a firstfeature over or on a second feature in the description that follows mayinclude embodiments in which the first and second features are formed indirect contact, and may also include embodiments in which additionalfeatures may be formed between the first and second features, such thatthe first and second features may not be in direct contact. In addition,the present disclosure may repeat reference numerals and/or letters inthe various examples. This repetition is for the purpose of simplicityand clarity and does not in itself dictate a relationship between thevarious embodiments and/or configurations discussed.

Further, spatially relative terms, such as “beneath,” “below,” “lower,”“above,” “upper” and the like, may be used herein for ease ofdescription to describe one element or feature's relationship to anotherelement(s) or feature(s) as illustrated in the figures. The spatiallyrelative terms are intended to encompass different orientations of thedevice in use or operation in addition to the orientation depicted inthe figures. The apparatus may be otherwise oriented (rotated 90 degreesor at other orientations) and the spatially relative descriptors usedherein may likewise be interpreted accordingly.

FIG. 1 is a flowchart of a method 100 of fabricating one or moresemiconductor devices in accordance with some embodiments of the presentdisclosure. The method 100 is an example, and is not intended to limitthe present disclosure beyond what is explicitly recited in the claims.Additional operations can be provided before, during, and after themethod 100, and some operations described can be replaced, eliminated,or relocated for additional embodiments of the method. The method 100 isdiscussed in detail below, including with reference a semiconductordevice 300 shown in FIG. 2 and processed in accordance with FIGS. 3Athrough 8. The method 100 may further be applied, in part, to form thesemiconductor device 900 illustrated in FIG. 9.

As will be shown, the semiconductor device 300 includes an image sensordevice. This does not necessarily limit the embodiments to any types ofdevices, any number of devices, any number of regions, or anyconfiguration of structures or regions beyond what is specificallyclaimed. For example, the provided subject matter can be applied infabricating planar field-effect transistor (FET) devices, FinFETdevices, multi-gate FET devices and a microelectro mechanical system(MEMS) device. Furthermore, the semiconductor device 300 may be anintermediate device fabricated during the processing of an IC, or aportion thereof, that may comprise static random access memory (SRAM)and/or other logic circuits, passive components such as resistors,capacitors, and inductors, and active components such as p-type FETs(PFETs), n-type FETs (NFETs), metal-oxide semiconductor field effecttransistors (MOSFET), complementary metal-oxide semiconductor (CMOS)transistors, bipolar transistors, high voltage transistors, highfrequency transistors, other memory cells, and combinations thereof.

Referring to FIG. 1, the method 100 starts at step 102 by receiving orproviding a semiconductor device. It is noted that FIGS. 2-6 are used anexemplary embodiment in particular directed to a device having twosubstrates bonded together an including an image sensor. However, onewill appreciate that the present methods and devices may also be appliedto different substrates, including bonded substrates and singlesubstrates. For example, in an embodiment, the SNF stack discussed indetail below is formed on a semiconductor substrate (e.g., backside)having one or more semiconductor devices formed thereon. This substratemay be bonded to another structure, or may be a single stand-alonesubstrate when the layers are applied.

Using FIG. 2 as exemplary, a semiconductor device 300 is provided. Theinitial structure 300 may include a first semiconductor device structure202 stacked on top of a second semiconductor device structure 204. Insome embodiments, the first semiconductor device structure 202 and/orthe second semiconductor device structure 204 are in wafer-form. In someembodiments, the first semiconductor device structure 202 and/or thesecond semiconductor device structure 204 have been previously dicedinto individual components (e.g., die).

In an embodiment, the first semiconductor structure 202 includes animage sensor, such as a backside illuminated image sensor (BSI), acomplementary metal-oxide-semiconductor (CMOS) image sensor (CIS), acharge-coupled device (CCD), an active-pixel sensor (APS), or apassive-pixel sensor. An image sensor may be fabricated by complementarymetal-oxide semiconductor (CMOS) process techniques known in the art. Inan embodiment, the second semiconductor device structure 204 includes asemiconductor device such as a transistor, capacitor, resistive element,micro-electromechanical system (MEMS) device, and/or other semiconductordevices. In an embodiment, the second semiconductor device structure 204includes an application-specific integrated circuit (ASIC) device. In anembodiment, the second semiconductor device structure 204 is a carriersubstrate or wafer. In an embodiment, the carrier substrate is glass.

The first and second semiconductor device structures, 202 and 204, maybe bonded together through suitable bonding techniques such as directbonding. In accordance with some embodiments, in a direct bondingprocess, the connection between the first and second semiconductordevice structures, 202 and 204, can be implemented throughmetal-to-metal bonding (e.g., copper-to-copper bonding),dielectric-to-dielectric bonding (e.g., oxide-to-oxide bonding),metal-to-dielectric bonding (e.g., copper-to-oxide bonding), or anycombination thereof. In some embodiments, the first and secondsemiconductor device structures, 202 and 204, are connected to eachother through suitable three-dimensional structure. An adhesion layermay also be used in the bonding process. Additionally, a thinningprocess may be performed to thin either or both semiconductorstructures. The thinning process may include a mechanical grindingprocess and/or a chemical thinning process, for example, applied to asurface (e.g., back surface) of the structures prior to or afterbonding.

The first semiconductor device structure 202 may include a substrate 210having a front surface 214 and a back surface 216 (an upside-downposition is shown in FIG. 2, however it is noted that all relative termsin the present disclosure do not imply an absolute direction but merelyused for ease of reference and describing a relational configuration).In an embodiment, the substrate 210 includes a bulk silicon substrate.Alternatively, the substrate 210 may comprise an elementarysemiconductor, such as silicon or germanium in a crystalline structure;a compound semiconductor, such as silicon germanium, silicon carbide,gallium arsenic, gallium phosphide, indium phosphide, indium arsenide,and/or indium antimonide; or combinations thereof. Possible examples ofthe substrate 210 also include a silicon-on-insulator (SOI) substrate.SOT substrates are fabricated using separation by implantation of oxygen(SIMOX), wafer bonding, and/or other suitable methods. Thus, in someexemplary substrates 210 also include an insulator layer. The insulatorlayer comprises any suitable material, including silicon oxide,sapphire, and/or combinations thereof. An exemplary insulator layer maybe a buried oxide layer (BOX). The insulator is formed by any suitableprocess, such as implantation (e.g., SIMOX), oxidation, deposition,and/or other suitable process. In some exemplary substrate 210, theinsulator layer is a component (e.g., layer) of a silicon-on-insulatorsubstrate.

The substrate 210 may include various features formed on and/or in thesubstrate (e.g., on and/or in the bulk silicon substrate or SOIsubstrate). For example, the substrate 210 may include various dopedregions. The doped regions may be doped with p-type dopants, such asboron or BF₂; n-type dopants, such as phosphorus or arsenic; orcombinations thereof. The doped regions may be formed directly on thesubstrate 210, in a P-well structure, in an N-well structure, in adual-well structure, or using a raised structure. The substrate 210 mayfurther include various active regions, such as regions configured foran N-type MOS transistor device and regions configured for a p-type MOStransistor device. The substrate 210 may also include various isolationfeatures. The isolation features separate various device regions in thesubstrate 210. The isolation features may include different structuresformed by using different processing technologies. For example, theisolation features include shallow trench isolation (STI) features. Theformation of a STI may include etching a trench in the substrate 210 andfilling in the trench with insulator materials such as silicon oxide,silicon nitride, or silicon oxynitride. The filled trench may have amulti-layer structure such as a thermal oxide liner layer with siliconnitride filling the trench. A chemical mechanical polishing (CMP) may beperformed to polish back excessive insulator materials and planarize thetop surface of the isolation features.

The components discussed above on the first semiconductor devicestructure 202 may be included in various passive and activemicroelectronic components disposed on and/or in the first semiconductordevice structure 202. These components may include image sensor elements220 (also referred to as pixels) and corresponding circuit elements 230.In an embodiment, the circuit elements 230 include peripheral circuitelements disposed on the first semiconductor device structure 202. Thesensor elements 220 detect intensity (brightness) of a radiationdirected toward the back surface 216 of the substrate 210. In FIG. 2,the sensor elements 220 are configured to correspond with a specificlight wavelength, such as a red (R), a green (G), or a blue (B) lightwavelength. In other words, the sensor elements 220 are configured todetect intensity (brightness) of a particular light wavelength. In someembodiments, the sensor elements 220 configured as pixels in a pixelarray.

The sensor elements 220 may include photodetectors, such as photodiodes,that includes light sensing regions (or photo-sensing region) 220R,220G, and 220B which detect intensity (brightness) of red, green, andblue light wavelengths, respectively. The light sensing regions (orphoto-sensing regions) 220R, 220G, and 220B may include doped regionshaving n-type and/or p-type dopants formed in the substrate 210. In someembodiments, the light sensing regions 220R, 220G, and 220B are n-typedoped regions, formed by a method such as diffusion and/or ionimplantation.

The sensor elements 220 further include various transistors, such as atransfer transistor, a reset transistor, a source-follower transistor, aselect transistor, other suitable transistors, or combinations thereof.The various transistors may include P-channel field effect transistors(PFETs), N-channel FETs (NFETs), metal-oxide semiconductor field effecttransistors (MOSFETs), CMOS transistors, FinFETs, high voltagetransistors, high frequency transistors, bipolar junction transistors,and/other suitable devices. The light sensing regions 2208, 220G, and220B and various transistors (which can collectively be referred to aspixel circuitry) allow the sensor elements 220 to detect intensity ofthe particular light wavelength. Additional circuitry, input, and/oroutputs may be provided to the sensor elements 220 to provide anoperation environment for the sensor elements 220 and/or supportcommunication with the sensor elements 220. This circuitry may beconsidered in the pixel or in a peripheral region of the substrate 210.

FIG. 2 illustrates an exemplary transistor element 230. The transistorelement 230 may be representative of the transistors of the pixelcircuitry discussed above, and/or be representative of a peripheralcircuit element. A peripheral circuit element may include one or morefield effect transistors. For example, the peripheral circuitry elementsinclude P-channel field effect transistors (PFETs), N-channel FETs(NFETs), metal-oxide semiconductor field effect transistors (MOSFETs),CMOS transistors, FinFETs, high voltage transistors, high frequencytransistors, bipolar junction transistors, resistors, capacitors,diodes, fuses, other suitable devices, and/or combinations thereof. Insome embodiments, the peripheral circuit elements are operable tointerface with or control the image sensor elements 220. In one example,a peripheral circuitry area includes peripheral circuit elements thatare not physically located within a pixel array area including the imagesensor elements and, instead, borders a periphery of a semiconductordie, on which, image sensor elements 220 are fabricated.

The semiconductor device structure 202 may include a dielectric layer(e.g., inter-level dielectric (ILD)) layer 240 formed over the frontsurface 214 of the substrate 210 for electric isolation purpose. The ILDlayer 240 may include silicon dioxide, silicon nitride, siliconoxynitride, TEOS oxide, phosphosilicate glass (PSG), borophosphosilicateglass (BPSG), fluorinated silica glass (FSG), carbon doped siliconoxide, amorphous fluorinated carbon, Parylene, polyimide, other suitablematerial, and/or combinations thereof. Common methods for forming theILD layer 240 include thermal oxidation, chemical vapor deposition(CVD), high-density plasma. CVD (HDP-CVD), physical vapor deposition(PVD), atomic layer deposition (ALD), spin-on deposition, and/or othersuitable deposition processes. In an embodiment, the ILD layer 240 mayinclude multiple layers made by different dielectric materials includingthose discussed above.

The first semiconductor device structure 202 may also includeinterconnection features (not shown) formed over the substrate 210 andconfigured to properly connect various features formed in or on thesubstrate 210, resulting in a functional designed circuit. For example,the interconnection features include multi-layer interconnect (MLI)having horizontal metal lines formed on multiple metal layers andcontact/via features to vertically connect metal lines of differentmetal layers or metal line lines to the substrate 210. In an embodiment,the interconnection features are formed in the ILD layer 240.

Additional features can be incorporated into the first semiconductordevice structure 202 and some of the features described above can bereplaced or eliminated for other embodiments of the first semiconductordevice structure 202.

The second semiconductor device structure 204 can include similar ordifferent elements, as compared to the first semiconductor devicestructure 202. For example, in an embodiment, the second semiconductordevice structure 204 may include a substrate 250 with surfaces, 252 and254, a primary element 260, a peripheral element 270 and dielectriclayers 280. Additional features can be incorporated into the secondsemiconductor device structure 204 and some of the features describedabove can be replaced or eliminated for other embodiments of the secondsemiconductor device structure 204. In an embodiment, the secondsemiconductor device structure 204 is omitted. It is noted that thesecond semiconductor device structure 204 may in fact in someembodiments not include a semiconductor device (e.g., handling wafer).

In an embodiment, one or more material layers (referred to as a stack ofmaterial layers) are formed over the back surface 216 of the substrate210. Depending on material layers' type, thickness, and receivingconditions during material layer formations, the composite stress of thematerial layer(s) may be compressive or tensile. Introduction of thisstress can lead the device 300 and/or the semiconductor device structure202 to have an unacceptable non-flatness (e.g., convex shape, concaveshape or other distortion). The non-flatness may cause adverse effectsin subsequent processes, such as an overlay error in the subsequentlithography patterning process to pattern the material layer(s). Theoverlay is the relative position between two or more layers of asemiconductor substrate such as, for example, a wafer. As semiconductorprocesses evolve to provide for smaller critical dimensions, and devicesreduce in size and increase in complexity including number of layers,the alignment precision between layers becomes increasingly moreimportant to the quality, reliability, and yield of the devices. Thus,the present disclosure provides a method to form a stress-neutralizedfilm pair (or a film stack) to reduce film-formation-stress inducednon-flatness of the semiconductor device 300.

Referring to FIGS. 1 and 3A, the method 100 then proceeds to step 104where a stress-neutralized film (SNF) stack 310 is formed over the backsurface 216 of the substrate 210. In the present embodiment, the SNFstack 310 includes a first film 312 (or a first group of films) and asecond film 314 (or a second group of films). The first film 312 has afirst type of film stress and a first film stress intensity (alsoreferred to as a stress value), while the second film 314 has a secondtype of film stress and a second film stress intensity (also referred toas a stress value). The second type of film stress is different than thefirst type of film stress; particularly, the second type of film stressis opposite of the first type of film stress. For example, in anembodiment, one of the first film 312 and the second film 314has/provides a compressive stress and another one of the first film 312and the second film 314 has/provides is tensile stress. In oneembodiment, the first type of film stress has compressive stress, whilethe second type of film stress is tensile stress. In an embodiment, thestress is provided by force/area represented by a number (or value) anda direction (e.g., +/−). The stress (force per area) for the first film312 may be a positive value (number) x; the stress (force per area) forthe second film 314 may be a negative value (number) x, where positiveis tensile stress and negative is compressive stress and x is the valueof the stress (e.g., force/area). For example, x may be a value in MPa.In an embodiment, the value (also referred to as intensity) of stress ofthe first and second films 312 and 314 are numbers within 10 percent,while the sign (or direction) is opposite (e.g., + and respectively). Inan embodiment, the intensity (or value) of stress of the first andsecond films 312 and 314 are substantially the same, while the sign (ordirection) is opposite (e.g., + and − respectively). Substantially thesame intensity includes those intensities that are exactly the same andwithin a few percent variation (e.g., <5%).

In the present embodiment, type, thickness and receiving conditionsduring formations of the first and second films, 312 and 314, iscontrolled such that, the value of the second film stress intensity isabout same as the value of first film stress intensity, but in anopposite direction. In other words, the second film stress compensates(or neutralizes) the first film stress. As a result, the SNF stack isformed with minimized stress-induced adverse impacts on flatness of thesemiconductor device 300.

Thus, in an embodiment, there may be a stress exhibited onto the surface216 of the device 202 from the deposition of the first film (e.g., 312)prior to the deposition of the second film (e.g., 314). This stressexhibited onto the surface 216 is then reduced or in some embodimentseliminated, upon the deposition of the second film (e.g., 314). Someembodiments this is because the opposite type of stress of the secondfilm serves to neutralize the stress provided by the first film.

The SNF stack 310 may be made by conductive materials, dielectricmaterials, and/or other suitable material. Examples of a conductivematerial may include tungsten (W), copper, copper alloy, coppermagnesium (CuMn), copper aluminum (CuAl), copper silicon (CuSi),aluminum (Al), and/or other suitable metal material. Examples of adielectric material may include silicon nitride, silicon carbide, and/orother suitable material. The SNF stack 310 may be formed by PVD, CVD,ALD, electroplating, and/or a combination thereof.

In some embodiments, the first and second films, 312 and 314, are samematerial formed by different deposition techniques. In an embodiment,the SNF stack 310 includes a pair of metal layers.

In an embodiment, the SNF stack 310 includes is a first tungsten (W)layer 312 formed by a first method and a second W layer 314 formed by asecond method. In an embodiment, the first method is one of PVD and CVDand the second method is the other one of PVD and CVD. In an embodiment,the PVD W layer 312 has compressive stress and the CVD W layer 314 hastensile stress. By choosing conditions of film deposition and thickness,the film stress intensity or value of the PVD W layer 312 is provided tobe substantially similar to the film stress intensity or value of theCVD W layer 314, the intensities of stress being provided in theopposite direction (+/−). In one embodiment, a thickness of the CVD Wlayer 314 is as same as the PVD W layer 312. For example, the thicknessmay be about 1000 Å.

In one embodiment, the PVD W layer 312 is deposited over the backsurface 216 of the substrate 210 and the CVD W layer 314 is depositedover the PVD W layer 312. In a further embodiment, there is a directinterface between layer 312 and layer 314. In another embodiment, theCVD W layer 314 is deposited over the back surface 216 of the substrate210 and the PVD W layer 312 is deposited over the CVD W layer 314. Againin a further embodiment, there is a direct interface between the layers312 and 314.

In an embodiment, one of the layers 312 or 314 is a tungsten layerformed using CVD. The CVD W layer (e.g., 314) is formed by usingtungsten hexafluoride (WF₆) precursor. As a result, the resultant CVD Wlayer has a composition including fluorine. This is illustrated by thefluoride peak shown in an energy-dispersive X-ray spectroscopy (EDX)spectrum, illustrated in FIG. 39. In FIG. 3B, the horizontal axis is theenergy (Kev), the vertical axis is the EDX signal and fluorine peakshows at about 0.677 Kev labeled in the legend as “F(K)”.

Alternatively, in some embodiments; the first and second films, 312 and314, are different materials. The materials (their thicknesses, theirdeposition methods) may be selected to provide similar intensity orvalue of stress, but in opposite directions as discussed above.

Referring again to FIG. 3A, in some embodiments, prior to forming theSNF stack 310, an anti-reflection coating (ARC) layer 302 is formed overthe back surface 216 of the substrate 210 and a dielectric layer 304 isformed over the BARC layer 302. In an embodiment, such as where the SNFstack 310 includes metal layers, a barrier layer 306 is formed over thedielectric layer 304 to prevent inter-diffusion and reactions with theSNF stack 310. The ARC layer 302 may include a nitride material, anorganic material; an oxide material and/or the like. The dielectriclayer 304 may include silicon oxide, silicon oxynitride, and/or othersuitable dielectric layer. The barrier layer 306 may include titanium(Ti), titanium nitride (TiN), tantalum nitride (TaN), tungsten nitride(WN), titanium silicon nitride (Ti SiN) or tantalum silicon nitride(TaSiN). One or more of the layers 302, 304 and 306 may be formed byPVD, CVD, metal-organic chemical vapor deposition (MOCVD) and ALD,and/or other suitable technique

Referring to FIGS. 1 and 4, method 100 proceeds to step 106 by forming apatterned photoresist layer 410 over the SNF stack 310. The patternedphotoresist layer 410 has a plurality of openings 415 and each of theopening 415 aligns to a respective light sensing region, 220R, 220G, and220B. In some embodiments, the patterned photoresist layer 410 is formedby a lithography process. An exemplary lithography process may includeforming a photoresist layer, exposing the photoresist layer by alithography exposure process, performing a post-exposure bake process,and developing the photoresist layer to form the patterned resist layer.

As has been mentioned previously, it is desired to form a patternedphotoresist layer over a substrate having an acceptable flatness toreduce overly error. In that regard, the SNF stack is formed withminimized stress-induced adverse impacts on flatness of thesemiconductor device 300. This in turn, an overlay error (between theopening 415 and the light sensing region 220R, or 220G, or 220B) inducedby non-flatness of the semiconductor device 300 is minimized.

Referring to FIGS. 1 and 5A, method 100 proceeds to step 108 where theSNF stack 310 is etched to form grid trenches 510 and grids (or pillar)520. In embodiment including additional layers, the additional layersmay also be etched. For example, the barrier layer 306 and a portion ofthe first dielectric layer 304 may be etched to form the grid trenches510 and grids 510 through the openings 415. In some embodiments, each ofgrid trenches 510 aligns (vertically) to a respective light sensingregion, 220R, 220G and 220B. For example, the grid trench 510 is formedsuch that the respective light sensing region is aligned within theboundaries of the trench 510.

The etch process for forming the grid trenches may include a wet etch, adry etch, and/or a combination thereof. The etch process may include adry etch, a wet etch, and/or a combination thereof. For an example, adry etch process may implement a fluorine-containing gas (e.g., CF₄,SF₆, CH₂F₂, CHF₃, and/or C₂F₆), a chlorine-containing gas (e.g., Cl₂,CHCl₃, CCl₄, and/or BCl₃), a bromine-containing gas (e.g., HBr and/orCHBr₃), an iodine-containing gas; other suitable gases and/or plasmas;and/or combinations thereof. As another example, a wet etching processmay comprise etching in diluted hydrofluoric acid (DHF); potassiumhydroxide (KOH) solution; ammonia; a solution containing hydrofluoricacid (HF), nitric acid (HNO₃), acetic acid (CH₃COOH); a standard cleansolution (SC1) having NH₄OH, H₂O₂ and H₂O and/or other suitable wetetchant. In some embodiments, a depth of etch is controlled that aportion of the dielectric layer 304 remains as a bottom portion of thegrid trench 520. The grid trenches 520 are etched using the patternedphotoresist and/or associated hard mask layers as masking elements.

After forming grid trenches 510 and grids 520, the patterned photoresistlayer 410 is removed by a proper process, such as wet stripping and/orplasma ashing, as shown in FIG. 5B. As a result, in an exemplaryembodiment, the grid 520 is formed such that it has the first dielectriclayer 304 as its bottom portion, the SNF stack 310 as its upper portion.

Referring to FIGS. 1 and 6, method 100 then proceeds to step 110 wherethe grid trench 510 is filled with a dielectric layer 610. Thedielectric layer 610 can extend above the grid trench 510, includingover above the grids 520. The dielectric layer 610 may include silicondioxide, silicon nitride, silicon oxynitride, TEAS oxide,phosphosilicate glass (PSG), borophosphosilicate glass (BPSG),fluorinated silica glass (FSG), carbon doped silicon oxide, amorphousfluorinated carbon, Parylene, polyimide, other suitable material, and/orcombinations thereof. The dielectric layer 610 may also include high-kdielectric materials, such as HfO₂, HfSiO, HfSiON, HfTaO, HfTiO, HfZrO,zirconium oxide, aluminum oxide, hafnium dioxide-alumina (HfO₂—Al₂O₃)alloy, other suitable high-k dielectric materials, and/or combinationsthereof. The dielectric layer 610 may be deposited by CVD, PVD, ALD,spin-on deposition, and/or other suitable deposition processes.

Referring to FIGS. 1 and 7, method 100 proceeds to step 112 by formingtrenches 620 within the dielectric layer 610. In an embodiment, thetrenches 620 align (vertically) to respective light sensing regions,220R, 220G and 220B. In some embodiments, the trenches 620 are formed byforming a patterned photoresist layer over the dielectric layer 610 andthen etching the dielectric layer 610 through the patterned photoresistlayer. In an embodiment, a depth of etch is controlled that a portion ofthe dielectric layer 610 remains as a bottom portion of the dielectrictrench 620. The etch process may include a wet etch, a dry etch, and/ora combination thereof.

Referring to FIGS. 1 and 8, method 100 proceeds to step 114 by formingcolor filters 710 and microlenses 720 over the back surface 216 of thesubstrate 210. In some embodiments, each of the color filters 710 alignswith the respective light sensing regions 220R, 220G, and 220B. Thecolor filters 710 are designed so that each filters through light of apredetermined wavelength. For example, the color filter 710 aligned withthe light sensing region 220R may be configured to filter throughvisible light of a red wavelength to the light sensing region 220R; thecolor filter 710 aligned with the light sensing region 220G may beconfigured to filter through visible light of a green wavelength to thelight sensing region 220G; or the color filter 710 aligned with thelight sensing region 220B may be configured to filter through visiblelight of a blue wavelength to the light sensing region 220B. The colorfilters 710 include any suitable material. In an example, the colorfilters 710 include a dye-based (or pigment-based) polymer for filteringout a specific frequency band (for example, a desired wavelength oflight). Alternatively, the color filters 710 may include a resin orother organic-based material having color pigments.

In the present embodiment; the microlenses 720, disposed over the backsurface 216 of the substrate 210, align with respective light sensingregions 220R, 220G, and 220B of the sensor elements 220. In someembodiments, the microlenses 720 are disposed over the color filters710. The microlenses 720 may be in various positional arrangements withthe sensor elements 220 and color filters 710, such that the microlens720 focuses an incoming incident radiation on the respective lightsensing regions 220R, 220G, and 220B of the sensor elements 220. Themicrolenses 720 include a suitable material, and may have a variety ofshapes and sizes depending on an index of refraction of the materialused for the microlens and/or a distance between the microlens andsensor elements 220. Alternatively, the position of the color filters710 and microlens 720 may be reversed, such that the microlenses 720 aredisposed between the back surface 216 of the substrate 210 and colorfilters 710. In present embodiment, the color filter 710 and themicrolense 720 are formed by a suitable process, such as deposition andpatterning.

Referring again to FIG. 8, in operation, the semiconductor device 300 isdesigned to receive a radiation 810 traveling towards the back surface216 of the substrate 210. In the depicted embodiment, the incidentradiation 810 is visual light. Alternatively, the radiation 810 could beinfrared (IR), ultraviolet (UV), X-ray, microwave, other suitableradiation type, or combinations thereof. The microlenses 720 direct theincident radiation 810 to the respective color filters 710. The lightthen passes through the color filters 710 to a corresponding sensorelement 220, specifically to respective light sensing regions 220R,220G, and 220B. The desired wavelengths of light (for example, red,green, and blue light) are more efficiently allowed to pass through tothe respective light sensing regions 220R, 220G, and 220B of the sensorelements 220. When exposed to the light, the light sensing regions 220R,220G, and 220B of the sensor elements 220 produce and accumulate(collect) electrons, which may be converted to voltage signals.

The semiconductor device 300 may include additional features, which maybe formed by subsequent processing. Additional steps can be providedbefore, during, and after the method 100, and some of the stepsdescribed can be replaced, eliminated, or moved around for additionalembodiments of the method 100.

Referring now to FIG. 9, illustrated is a semiconductor device 900. Thedevice 900 may include a substrate 210. The substrate 210 may be asemiconductor substrate such as a silicon substrate. In otherembodiments, the semiconductor substrate 201, the substrate mayalternatively or additionally include other suitable semiconductormaterial, such as germanium (Ge), silicon germanium (SiGe), siliconcarbide (SiC), gallium arsenic (GaAs), diamond, indium arsenide (InAs),indium phosphide (InP), silicon germanium carbide (SiGeC), galliumindium phosphide (GaInP), and/or other suitable materials. The substrate210 may have any number of features of semiconductor devices disposedthereon including those features associated with planar bulkmetal-oxide-semiconductor field-effect transistors (MOSFETs), multi-gatetransistors (planar or vertical) such as FinFET devices, gate-all-around(GAA) devices, Omega-gate (Ω-gate) devices, or Pi-gate (Π-gate) devices,as well as strained-semiconductor devices, silicon-on-insulator (SOI)devices, partially-depleted SOI devices, fully-depleted SOI devices, orother devices as known in the art. The substrate 210 may include otherdevice such as MEMs devices, capacitors, resistors, image sensors, LCDdevices, and/or other suitable devices.

The device 900 includes the layers 312 and 314, which may besubstantially similar to as discussed above. For example, the layers 312may include stresses that together, neutralize one another (e.g.,compressive and tensile). The layers 312 and 314 may be patterned usingphotolithography methods including as discussed above. Additional layersmay be formed on and/or under the layer 312 and 314, including asdiscussed above. In some embodiments, the layers 312 and 314, asdiscussed above, serve to reduce a cumulative stress introduced to thesubstrate 210, for example, providing for a relative ‘flatness’ of thesubstrate 210.

Based on the above, it can be seen that the present disclosure providemethods of forming a stack of film with minimized stress-induced adverseimpacts on flatness of a substrate. The method employs form a pair offilms, which has opposite stress type and same stress intensity (value).The method demonstrates suppressing film-stress-induced adverse impactson flatness of the substrate. The method in some embodiments minimizesthe overlay error caused by non-flatness of the substrate.

The present disclosure provides many different embodiments offabricating a semiconductor device that provide one or more improvementsover existing approaches. In one embodiment, a method for fabricating asemiconductor device includes forming a first film having a first filmstress type and a first film stress intensity over a substrate andforming a second film having a second film stress type and a second filmstress intensity over the first film. The second film stress type isdifferent than the first film stress type. The second film stressintensity is about same as the first film stress intensity. The secondfilm compensates stress induced effect of non-flatness of the substrateby the first film.

In yet another embodiment, a method includes providing a substratehaving a imaging sensor element, forming a pair of films over thesubstrate. The pair of films has a first film having compressive stressand a first film stress intensity and a second film having tensilestress and a second film stress intensity. The second film stressintensity is about same as the first film stress intensity and thesecond film compensates stress induced effect of non-flatness of thesubstrate by the first film. The method also includes forming apatterned photoresist layer over the pair of films. The patternedphotoresist layer has an opening aligns to the imaging sensor element.The method also includes etching the pair of films through the openingto form a trench and a pillar.

In yet another embodiment, a method includes forming a pair of filmsover the substrate. The pair of films has a first film havingcompressive stress and a first film stress intensity and a second filmhaving tensile stress and a second film stress intensity over the firstfilm. The second film stress intensity is about same as the first filmstress intensity and the second film compensates stress induced effectof non-flatness of the substrate by the first film. The method alsoincludes patterning the pair of films by lithography process and etchingprocess.

The foregoing outlines features of several embodiments so that thoseskilled in the art may better understand the aspects of the presentdisclosure. Those skilled in the art should appreciate that they mayreadily use the present disclosure as a basis for designing or modifyingother processes and structures for carrying out the same purposes and/orachieving the same advantages of the embodiments introduced herein.Those skilled in the art should also realize that such equivalentconstructions do not depart from the spirit and scope of the presentdisclosure, and that they may make various changes, substitutions, andalterations herein without departing from the spirit and scope of thepresent disclosure.

1.-20. (canceled)
 21. A device comprising: an image sensor elementdisposed in a substrate; and a metal layer stack disposed over thesubstrate, wherein the metal layer stack includes an opening that isaligned with the image sensor element, and further wherein the metallayer stack includes a first metal layer disposed over a second metallayer, the first metal layer including a first metal and the secondmetal layer including a second metal and fluorine.
 22. The device ofclaim 21, wherein the first metal is tungsten and the second metal istungsten.
 23. The device of claim 21, wherein a thickness of the firstmetal layer is substantially the same as a thickness of the second metallayer.
 24. The device of claim 23, wherein the thickness of the firstmetal layer and the thickness of the second metal layer is about 1000 Å.25. The device of claim 21, further comprising a third metal layerdisposed between the second metal layer of the metal layer stack and theimage sensor element, the third metal layer including a third metal. 26.The device of claim 25, wherein the first metal and the second metal arethe same and the third metal is different than the first metal and thesecond metal.
 27. The device of claim 25, further comprising adielectric layer disposed between the third metal layer and the imagesensor element.
 28. The device of claim 21, wherein the substrateincludes a first surface opposite a second surface, wherein the imagesensor element is disposed at the first surface of the substrate and themetal layer stack is disposed over the second surface of the substrate.29. A device comprising: an image sensor device; and a metal griddisposed over the image sensor device, wherein the metal grid includes:a first metal film consisting of a first metal having a first stresstype, a second metal film consisting of a second metal having a secondstress type, wherein the first stress type is opposite the second stresstype, and an opening aligned with a light sensing region of the imagesensor device, wherein the opening extends through the first metal filmand the second metal film.
 30. The device of claim 29, furthercomprising a substrate, wherein the light sensing region of the imagesensor device is disposed at a front surface of the substrate and themetal grid is disposed over a back surface of the substrate.
 31. Thedevice of claim 29, wherein the first metal is tungsten and the secondmetal is tungsten.
 32. The device of claim 31, wherein the second metalfilm includes fluorine.
 33. The device of claim 29, wherein a thicknessof the first metal film is substantially the same as a thickness of thesecond metal film.
 34. The device of claim 29, wherein the first metalfilm is only one metal layer and the second metal film is only one metallayer.
 35. A method comprising: depositing a first metal layer includinga first metal over a substrate, wherein an image sensor element isdisposed in the substrate; depositing a second metal layer over thefirst metal layer, wherein the second metal layer includes a secondmetal and fluorine; and patterning the first metal layer and the secondmetal layer to include an opening that is aligned with the image sensorelement disposed in the substrate.
 36. The method of claim 35, whereinthe depositing the first metal layer includes performing a physicalvapor deposition process and the depositing the second metal layerincludes performing a chemical vapor deposition process.
 37. The methodof claim 35, wherein the depositing the first metal layer and thedepositing the second metal layer are controlled to achieve a value ofstress intensity of the first metal layer that is substantially the sameas a value of stress intensity of the second metal layer.
 38. The methodof claim 35, further comprising: forming a dielectric layer over thesubstrate before depositing the first metal layer; and wherein thepatterning the first metal layer and the second metal layer extends theopening into the dielectric layer.
 39. The method of claim 38, furthercomprising: depositing a third metal layer over the dielectric layerbefore depositing the first metal layer, wherein the third metal layerincludes a third metal; and wherein the patterning the first metal layerand the second metal layer extends the opening into the third metallayer.
 40. The method of claim 35, further comprising filling theopening with a dielectric layer.